Exploding 123A Batteries?

 
 
 
June 2006
         

For some reason, I have been getting a lot of questions about the possibility of 123A lithium cells exploding or causing a flashlight to burst.

Some of this is the result of third-, fourth-, or fifth-party stories about someone who had a flashlight burst, or someone who heard about someone who read something on the internet that a 123A powered flashlight burst, etc.

Some of it is due to marketers' fear-mongering in order to sell products that don't use 123A cells and instead use alkalines as a "safe alternative".

Could it happen to me?

Yes, it could happen.

You could also get struck by lightning next time you walk outside.

A meteor could come crashing though your house.

Your computer monitor could burst into flames right now.

None of those things happening are very likely, are they?

Yes, I'm trying to make a point.

123A cells have been known to vent, outgas, and cause lights to burst violently. Sort of like your chances of getting struck by lightning or winning the lottery. It happens, but very rarely.

When those unique and exceptional events happen, everyone hears about them and then assumes it's the norm. This is how insurance companies stay in business and why state lotteries are so popular.

Chances are very good that you'll never have a problem with 123A cells. I have used many, many 123A lithium cell flashlights, have burned through hundreds of 123A lithium cells, and have never had a problem. In fact, millions of people have used millions of 123A cell batteries without any problems.

Since there really aren't any statistical numbers related to 123A cells bursting, I'm willing to bet that your chance of getting into a car accident in your lifetime is much, much higher than the chances of having one of your 123A cells burst in a flashlight.

Why does it happen?

Keeping it simple, two things have to occur for a light to burst:

1) First, you need something to create a lot of pressure.

When 123A lithium cells short out or overheat they release a lot of energy very quickly in the form of hot gasses. This creates the pressure. The main reason for this happening is the use of two cells of different charge levels. When used, the one good cell tries to both power the device and charge the bad cell and one or both cells overheat. How can you tell if you have a bad cell? Other than testing it, you can't.

2) Second, in order for a flashlight or anything else to burst violently, you need an airtight container in which the pressure can build up.

A metal flashlight with O-ring seals is very good at containing pressure, to a point. When the pressure builds up enough, something fails and it bursts. Since there is usually a lot of pressure built up, pieces tend to fly at high enough velocity to cut skin and damage property.

If the pressure cannot build up because the light isn't sealed well, it will usually hiss or pop, release the pressure, and we never hear about it from that person because it's "no big deal".

How do I prevent it from happening?

Following some simple rules will help ensure that you don't have any problems. As is to be expected, prevention is the best medicine.

Use only good quality or proven brands, don't mix cell brands, don't mix cells of different charge levels in the same device, and don't mix-and-match partially used cells that you may have lying around.

Although not a guarantee that you won't have any problems, this will go a long way in helping.

If you have ever actually taken the time to read the instructions for almost any flashlight, the advice above should sound familiar. Really, this advice applies to all power storage cells, not just 123A lithium cells. Lithium cells are a bit different because of how quickly they can discharge all of their power. This simple fact of their design makes caution more important, but caution should be exercised with any power storage cells.

A trend has emerged that implicates 123A cells manufactured in China as the major source of the "bursting cell" problems. US supplied 123A cells (such as Duracell or Energizer) are much more expensive and apparently have higher quality control. The China supplied batteries are much cheaper (hence their popularity) but consistency in performance seems to be a bit of an issue. You could just buy US brands, but at $10 a pair, it gets very expensive very fast.

For less than the cost of 3 pair of the US made cells, you could invest in a tester and test the cells you buy. This is probably a very good idea if you use inexpensive Chinese manufactured cells. I use the ZTS Mini-MBT which I recently picked up from Thomas Distributing. The meter tells you if the cell is at < 20% capacity, 20%, 40%, 60%, 80% or 100%. When working with multi-cell flashlights, I now make sure to use only cells that have a matched initial state-of-charge. If a brand new cell tests poorly, it's not necessarily dead. It should be matched with another brand new cell that matches the test results when used in multi-123A cell applications. I test all my cells and label them with a sharpie marker. They get one of the following numbers: 0 (< 20%), 2 (20%), 4 (40%), 6 (60%), 8 (80%), or 10 (100%). Only cells with the same number are used together.

You could also use only single-123A cell lights. Some excellent lights are powered by only one 123A cell. The few problems that happen appear only to occur when you use more than one 123A cell in series.

An Experiment:

I tested a bunch of older inexpensive 123A cells I had lying around. Testing cycle was repeated with a ZTS Mini-MBT tester until 3 consistent readings were shown on the meter scale. The meter reads < 20% (no reading), 20%, 40%, 60%, 80%, 100%. Batteries that read less than 100% aren't really dead and may provide long runtimes. However they may not be delivering the same current and/or voltage as cells with other readings.

Here are the results of testing 64 unused, shrink-wrapped cells:

Charge Indicated
Number of Cells

100%

18

80%

8

60%

10

40%

10

20%

8

< 20%

10

Obviously I could have easily put a < 20% cell and a 100% cell in the same light, but that doesn't mean that the batteries would have burst. It does, however, mean that some of the energy from that 100% cell is probably going to be wasted trying to bring the < 20% cell up to par and the chances of a burst cell are probably increased.

To discover the actual effect of mixing cells of different known initial charge state, I did some runtimes with the same 2-cell light loaded with two < 20% cells, two 100% cells, and with a single < 20% and 100% cell. I strongly recommend against mixing cells of different known charge, so don't purposely try this!

The runtimes were done with a Streamlight Scorpion, which has a pretty strong constant draw on the cells. I did not test the output for each of these combinations. I didn't use a regulated light because I wanted to see the impact on the runtime caused by a direct draw from the batteries.

Here are the results:

The red line is two cells that read 100% on the meter.
The blue line is two cells that read < 20% on the meter.
The green line is the result of mixing one "< 20%" cell and one "100%" cell in the light.

Even though the blue line runtime was done with two cells that read "< 20%" on the meter's display, they provided decent runtime in the light, although reduced runtime relative to two "100%" cells.

The most telling thing is that when the runtime was done with one "100%" cell and one "< 20%", runtime was reduced dramatically - even more so than running with two "< 20%" cells.

Using matched cells in a light will apparently provide some benefits, including increased runtimes and, I would expect, reduced chances of having a cell burst.

 

Conclusion:

Don't let the fear of this rare event limit your illumination options. Some of the brightest, lightest weight, and generally "best" lights are powered by 123A lithium cells. Often after trying one, it is practically impossible to go back to that favorite old 2-AA alkaline light you've carried for years. Take it from someone who has experienced this first-hand. Be aware, however, that it CAN happen and take appropriate precautions.


More Information:

For more information about a few actual documented incidents of this happening, please see the following CandlePowerForums.com threads. Registration is not required to read the articles. Keep in mind that the folks frequenting the Forums collectively burn through hundreds of thousands of 123A cells each year and some of these reports are from incidents outside of the forums.

http://candlepowerforums.com/vb/showthread.php?t=78843

http://candlepowerforums.com/vb/showthread.php?t=114455

One article at the GeoCaching forums where this happened to one individual:

http://forums.groundspeak.com/GC/index.php?showtopic=132932&st=0&p=2223457&#entry2223457
(Scroll to top of thread for the story behind the picture. Some of the pictures in the article are copies from the first CandlePowerForums article, above.)

CPSC Recall page related to 123A cells bursting:

DOT Article regarding a fire caused by shipment of 123A batteries damaged during offloading.

Information about 123A cells in general:

http://data.energizer.com/PDFs/123.pdf

http://candlepowerforums.com/vb/showthread.php?p=1381798#post1381798 (Disassembled 123A; DO NOT TRY THIS!)

http://candlepowerforums.com/vb/showpost.php?p=768005&postcount=1 (123A battery shootout)

http://data.energizer.com/PDFs/lithiummangdioxide_psds.pdf (Energizer safety sheet)

http://www.sanyo.com/batteries/pdfs/lithium_E.pdf (Sanyo safety sheet)

http://www.panasonic.com/industrial/.../Panasonic_Lithium_SafetyPrecautions_UL.pdf (Panasonic safety sheet)


Even More Information:

This next section is a large group of threads/links from CandlePowerForums which I "borrowed" from a thread about 123A cells exploding. It may contain a number of the threads I have above, but is the largest amount of posts/information I have found in one place about this topic.

From THIS THREAD on CandlePowerForums. Links collected by CPF members "Braddah_Bill" and "g36pilot".

 

G2 explosion by Kumar 762
http://www.candlepowerforums.com/vb/...d.php?t=140755

more on the G2 explosion *PICS*
http://www.candlepowerforums.com/vb/...d.php?t=140717

Cyclops Flashlight Explosion
http://www.candlepowerforums.com/vb/...d.php?t=122500

Primary Lithium battery explodes!
http://candlepowerforums.com/vb/show...3&page=1&pp=30

CR123A meltdown in PM6: What happened?
http://www.candlepowerforums.com/vb/...ad.php?t=91245

ROAR of the Pelican (CR123 Explosion during use, firsthand account)
http://www.candlepowerforums.com/vb/...8&page=1&pp=30

Accident w/Amondotech 123s and SF M2 Detonator G&P Tailcap Chop KL3 Head!
http://www.candlepowerforums.com/vb/...9&page=1&pp=30

Flash Amp Testing
http://www.candlepowerforums.com/vb/...ad.php?t=28692

Battery explosion with Fenix P1D
http://www.candlepowerforums.com/vb/...ight=exploding

My Aleph 1 Exploded and cought on fire.
http://www.candlepowerforums.com/vb/...d.php?t=170187

123 Primary Lithium cell info/testing/links
http://www.candlepowerforums.com/vb/...ight=exploding

Safety Concern Re: Lithium Multicurrent Universal Fast Smart Charger.
http://www.cpfmarketplace.com/mp/sho...d.php?t=157673

 

Battery Venting Incidents:

Original Incident Post PM6 w/BS 123s
http://candlepowerforums.com/vb/showthread.php?t=120888&page=1&pp=30

CR123 Electrolyte Fume Exposure Incident
http://candlepowerforums.com/vb/showthread.php?t=141137&page=1&pp=30

Another PM6 incident
http://www.candlepowerforums.com/vb/showthread.php?t=78843

Another documented venting incident with Pelican PM6 flashlight
http://www.candlepowerforums.com/vb/showthread.php?t=91245

PM6 w/SF123
http://candlepowerforums.com/vb/showpost.php?p=1460697&postcount=478

Same as above
http://candlepowerforums.com/vb/showpost.php?p=1461982&postcount=490

BS battery venting in PM6 during test with 60/100 capacities.
http://candlepowerforums.com/vb/showpost.php?p=1485475&postcount=613

Photos of vented BS battery in PM6 during test with 60/100 capacities.
http://candlepowerforums.com/vb/showpost.php?p=1485564&postcount=614

PM6 vents 3 for 3 in testing
http://candlepowerforums.com/vb/showpost.php?p=1487003&postcount=626

Pelican PM6 info
http://flashlightreviews.com/reviews/pelican_m6.htm

SL Scorpion w/Panasonic 123s Venting
http://candlepowerforums.com/vb/showpost.php?p=1364309&postcount=1

SF 9P w/unknown CR123s venting w/ injury
http://forums.groundspeak.com/GC/index.php?showtopic=132932&st=0&p=2223457&#entry22 23457

Cyclops flashlight w/Cyclops batts explode
http://candlepowerforums.com/vb/showthread.php?t=122500

Cyclops incident thread
http://candlepowerforums.com/vb/showthread.php?t=122500&page=1&pp=30

Li AA explodes
http://www.candlepowerforums.com/vb/showthread.php?t=121303

Amondotech 123’s vent
http://candlepowerforums.com/vb/showpost.php?p=1535329&postcount=1

Chinese PW Powerstation CR?123 in PD1 venting
http://www.candlepowerforums.com/vb/showthread.php?t=169038

Mod’d light/AmondoTech CR123s
http://candlepowerforums.com/vb/showpost.php?p=1536209&postcount=38

WE 6v w/BS 123’s
http://www.candlepowerforums.com/vb/showthread.php?t=157900

Browning flashlight recall (2 reports)
http://www.consumeraffairs.com/recalls04/browning.html

Dorcy recall w/house fire reported
http://www.consumeraffairs.com/recalls04/dorcy.html

A&T Fuji Power CR123A Recall (5 venting incidents reported)
http://www.cpsc.gov/cpscpub/prerel/prhtml03/03195.html

AED explosion w/injuries
http://www.cdc.gov/niosh/fire/reports/face9939.html

Ledwav Z5 weapon light incident
http://www.glocktalk.com/showthread.php?&threadid=537333

CR123 systems banned from nuclear power plant after fire.
http://www.candlepowerforums.com/vb/showthread.php?t=71161

Defective Chinese light on Air Canada
http://candlepowerforums.com/vb/showthread.php?p=1529062#post1529062

Aimshot Xenon Illuminator model TX-125 weapon light meltdown
http://www.jouster.com/cgi-bin/guntalk/config.pl?noframes;read=25245

Japanese blog/venting incident
http://www.xanga.com/Cr0c0/490345068/item.html

Aleph 1 w/BS CR123’s vent/explode
http://www.candlepowerforums.com/vb/showthread.php?t=170187

Material Safety Data Sheets & Other Chemistry Data:

HF: HydroFluric Acid

HF data
http://en.wikipedia.org/wiki/Hydrofluoric_acid

HF data
http://www.emedicine.com/emerg/topic804.htm

HF MSDS
http://www.bu.edu/es/labsafety/ESMSDSs/MSHydFluoricAcid.html#anchor888417

GP MSDS
http://www.gpbatteries.com.hk/pic/MSDS_PhotoLithum.pdf

MSDS/PSDS Li-SOCl2
http://www.seabird.com/pdf_documents/msds_sheets/Saft_3.6VLithiumAA.pdf

Li HexaFl
http://www.gfschemicals.com/Search/MSDS/2534MSDS.PDF

Duracell MSDS
http://www.duracell.com/oem/safety/pdf/2003_5C.pdf

LG18650 MSDS
http://www.hp.com/hpinfo/globalcitizenship/environment/pdf/msds_lg_liion.pdf

Batteryspace MSDS w/HF warning
http://www.batteryspace.com/prod-specs/MSDSLiion.pdf

Technical Data:

Duracell Batt Construction Pictorial
http://www.duracell.com/procell/chemistries/lithium.asp#

Duracell Safety and Reliability, UL Testing
http://www.duracell.com/oem/primary/Lithium/safety.asp#underwriters

CR123 disected
http://candlepowerforums.com/vb/showthread.php?p=1389277

Duracell 123 Engineering Data Sheet
http://www.duracell.com/Procell/pdf/Li123_US_OS.pdf

Energizer 123 Engineering Data Sheet
http://data.energizer.com/PDFs/123.pdf

Government & Industry Reports:

Federal Register Vol. 69, No. 240 December 15, 2004
http://www.iata.org/.../US_DOT_HM224E_Lithium_Battery_Ban.pdf

Li-Ion Batteries In Transport
http://www.wrf.com/docs/publications/12574.pdf

Dealing w/inflight lithium battery fires
http://www.caa.co.uk/docs/33/CAPAP2003_04.PDF

DOT Flammability Assessment CR123s
http://www.mobilit.fgov.be/data/aero/FAALiBaFiRe.pdf

NTSB fire tests- Compartment PSI increases
http://www.ntsb.gov/events/2006/PhiladelphiaPA/Exhibits/350561.pdf

(unknown)
http://www.fire.tc.faa.gov/pdf/systems/Lithium-ion_battery_04112006.pdf

UN Dangerous Goods/Li Testing 12/2000
http://www.unece.org/trans/doc/2000/ac10/ST-SG-AC10-27a2e.pdf

UN Dangerous Goods Li-Ion Discussion 2005
http://www.unece.org/trans/doc/2005/ac10c3/ST-SG-AC10-C3-2005-43e.doc

KMEM battery vent NTSB 2004
http://www.ntsb.gov/publictn/2005/HZB0501.htm

Risk & Financial Analysis Encouraging Off-Shore Li-Ion Production
http://www.atp.nist.gov/eao/wp05-01/chapt4.htm

Battery Transportation & Waste Regulation
http://www.wrf.com/docs/events/1117.pdf

NIOAH exploding flashlight risk
http://www.cdc.gov/niosh/fact0002.html

Primary Li Batt Limited On Pax Aircraft
http://www.rayovac.com/technical/pdfs/tech_uslithium.pdf

Li-On, The Ideal Rechargeable? No
http://www.batteryuniversity.com/partone-5.htm

Destructive Testing:

Li-Ion Nail Penetration Test Video
http://www.a123systems.com/html/tech/safety.html RCR123

YouTube Intentional Battery Vent
http://www.youtube.com/watch?v=vS2hGoJVmlA

 

 

 

 
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